Hi Bill,
That's a great question and there is an easy workaround. Before you choose Primatte from the Filter menu, you can use Photoshop's tools to create a mask around the green area that you want to isolate. For instance, circle around the green area with the Lasso or Marque tool.
Whatever is INSIDE the mask will be recognized and worked upon by Primatte, so you will need to invert the mask using the Select>Invert command. Once you've done this, open up Primatte and you'll see that as you work in the Primatte interface, the plugin doesn't touch whatever is outside the Photoshop mask.
Regarding the hat's green touching the background's green, probably the only way around this issue is to draw a careful mask with the Photoshop tools. If you'd like to email me an image or two, I can give you further assistance by eyeing up the photos or doing a quick experiment. My email is debbie@digitalanarchy.com.
I do know of a new forum called chromakey.com. A great photographer and friend, Neal Martin, recently set it up. However, I don't know much about its operation or response time.
regards -debbie
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Debbie Rich
debbie@digitalanarchy.com
Digital Anarchy
Filters for Photography & Photoshop
http://www.digitalanarchy.com
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Thanks a lot for sharing this, even thought I didn't ask the question. It helped me a lot.